Ladder Polymer Science: Innovation through Ladder Bonding

A02 Ito’s paper on all-hydrocarbon polyspirenes was published in Org. Lett.

A02 Ito’s paper on all-hydrocarbon polyspirenes was published in Org. Lett., and highlighted as a front cover picture. Congratulations.

Key Points of This Study: Synthesis of novel polyspyrene molecules composed exclusively of hydrocarbons—suggesting extension of “Spiro-Conjugation” without interatomic bonds
・Synthesis of novel polyspyrene molecules composed exclusively of hydrocarbons, previously unachieved.
・Achieved extension of the polyspyro structure through repeated three-step reaction pathways starting from anthraquinone.
・Identification of the extension of “spiro-conjugated” structures without interatomic bonds and its impact on photophysical properties.